57Fe-Mössbauer spectroscopy on natural eosphorite-childrenite-ernstite samples     

Geraldo Magela da Costa  Ricardo Scholz  Joachim Karfunkel  Vladimir Bermanec  Mário Luiz de Sá Carneiro Chaves 《Physics and Chemistry of Minerals》2005,31(10):714-720

Samples of the eosphorite-childrenite [(Mn²⁺, Fe²⁺)AlPO₄(OH)₂H₂O] series from Divino das Laranjeiras and Araçuaí (Minas Gerais State) and Parelhas (Rio Grande do Norte State) pegmatites have been investigated by X-ray diffraction, microprobe analysis and Mössbauer spectroscopy at 295 and 77 K. The Mössbauer spectra of ernstite [(Mn²⁺, Fe³⁺)AlPO₄(OH)_2-xO_x] showed the existence of ferric ions in both A and B sites, whereas ferrous ions seem to be located exclusively in the A site. Nonoxidised samples show ferrous ions located in both sites, and no Fe³⁺ could be detected. The interpretation of the Mössbauer spectra of both, oxidised and nonoxidised samples, is difficult because the hyperfine parameters of these minerals are rather similar, rendering it difficult to make proper site assignments.  相似文献   

云南东川地区含金剪切带型金矿   总被引：9，自引：3，他引：9  

张翼飞 《云南地质》2003,22(4):360-370

云南东川地区含金剪切带型金矿，1995年11月由云南八0七队从蒋家湾开始发现首个金矿段，继而向北勘查扩大到七角地和新山矿段。随着勘查的深入及大比例尺地质图填制，证实该金矿处在剪切破碎带中，并具大型以上规模前景。特别是新山矿段中砂糖状石英脉的发现，和矿体顶板接触带构造透镜体、糜棱岩的存在，含金韧性剪切带型金矿的特征渐趋明朗。云南昆阳群中多处发现含金石英脉，从拖布卡金矿的事实，促使我们重新考虑其中是否亦有剪切带型金矿类型。观念的转变，有可能促进昆阳群找金的突破。  相似文献   

The nature of fluids during pegmatite development in metamorphic terrains: Evidence from Hamadan complex,Sanandaj-Sirjan metamorphic zone,Iran     

F. Masoudi  B. Mehrabi  M. Rezai Aghdam  B. W. D. Yardley 《Journal of the Geological Society of India》2009,73(3):407-418

In the Sanandaj-Sirjan zone of metamorphic belt of Iran, the area south of Hamadan city comprises of metamorphic rocks, granitic batholith with pegmatites and quartz veins. Alvand batholith is emplaced into metasediments of early Mesozoic age. Fluid inclusions have been studied using microthermometry to evaluate the source of fluids from which quartz veins and pegmatites formed to investigate the possible relation between host rocks of pegmatites and the fluid inclusion types. Host minerals of fluid inclusions in pegmatites are quartz, andalusite and tourmaline. Fluid inclusions can be classified into four types. Type 1 inclusions are high salinity aqueous fluids (NaCl_eq >12 wt%). Type 2 inclusions are low to moderate salinity (NaCl_eq <12 wt%) aqueous fluids. Type 3 and 4 inclusions are carbonic and mixed CO₂-H₂O fluid inclusions. The distribution of fluid inclusions indicate that type 1 and type 2 inclusions are present in the pegmatites and quartz veins respectively in the Alvand batholith. This would imply that aqueous magmatic fluids with no detectable CO₂ were present during the crystallization of these pegmatites and quartz veins. Types 3 and 4 inclusions are common in quartz veins and pegmatites in metamorphic rocks and are more abundant in the hornfelses. The distribution of the different types of fluid inclusions suggests that CO₂ fluids generated during metamorphism and metamorphic fluids might also contribute to the formation of quartz veins and pegmatites in metamorphic terrains.  相似文献   

云母:花岗岩-伟晶岩稀有金属成矿作用的重要标志矿物   总被引：4，自引：1，他引：3  

王汝成  谢磊  诸泽颖  胡欢 《岩石学报》2019,35(1):69-75

云母是花岗岩、伟晶岩中的重要造岩矿物,不仅是整个岩浆阶段的结晶产物,而且也是热液过程的参与者。作为层状硅酸盐矿物,层间或八面体位置上可容纳锂、铷铯、锡、铌钽等稀有金属。本文结合前人研究积累和作者近年来的研究成果,阐述了云母作为一个重要的稀有金属成矿标志矿物的矿物学特征。铁锂云母-锂云母是稀有金属成矿作用中重要的锂矿物,同时云母中锂含量可以反映花岗岩的分异程度。铷、铯可以置换云母层间钾,在高演化花岗岩、伟晶岩中可以形成铷、铯为主的云母(既可以是锂云母系列,也可以是黑云母系列)。黑云母是稀有金属花岗岩中一个特殊的矿物。准铝质含锡花岗岩中黑云母锡含量可达100×10~(-6),其锡含量可以指示其锡成矿能力。稀有金属花岗岩中,常见的是铌钽氧化物矿物。但是最近研究发现,黑云母中铌可以超常富集(超过1000×10~(-6)),成为稀有金属花岗岩中最重要、甚至唯一的铌矿物,形成一种以富铌黑云母为特色的新类型稀有金属花岗岩,并可能代表了一种新型的潜在铌资源。基于云母在花岗岩中的重要性和结构的特殊性,今后要利用微区成分和结构分析技术,加强对云母中稀有金属晶体化学的研究,以及进一步揭示云母对稀有金属成矿的特殊重要意义。  相似文献   

四川康定县贵台子金矿地质特征及成因模式     

和玉红 《云南地质》2014,(4):583-587

康定贵台子金矿位于大渡河金多金属成矿远景区中段,矿体主要受构造及岩浆岩控制,成矿流体来自深部,矿床类型属石英脉型金矿.在康定杂岩高含金性的基础上,通过中—新生代以来的构造—热事件作用,金元素再次活化富集和迁移.在有利部位重新就位形成工业矿体.  相似文献   

云南元阳小河边石英脉型金多金属矿     

吕会梅  和松文  彭一航 《云南地质》2014,(1):58-61

金矿赋存于晚古生代第一期闪长岩体、小新街断裂两侧次一级断层破碎带含金石英脉中.原生矿石中以粒状自然金为主,粗粒—细粒.尚见叶片状、针尖状、不规则状金.含金石英脉有四个成生阶段,以第二、第三阶段含金性较好.矿床属中—高温闪长岩次级压扭性断裂中石英脉型金矿.  相似文献   

The Bizielle vein (valle de Gistain): A case of iron oxide transformations at the Pyrenees of Spain     

Irene DeFelipe  Isabel Fanlo  Ester Mateo  Ignacio Subías 《Chemie der Erde / Geochemistry》2014

The Bizielle vein has some unique features among the Pyrenean alpine veins that allow us to address the question of the nature of iron oxides transformations under low temperature hydrothermal conditions, which is well known to prevailed over wide areas of western Europe between early Triassic to early Cretaceous times. Isotopic studies indicate a deep-seated origin of the ore-forming fluids and suggest that the metals were leached from the Variscan basement (mainly from granites). Isotopic geothermometry and regional evidences point to a 250 °C and reducing fluid, being SH₂ the predominant S specie. Under such conditions, the proposed in situ deposition of hematite is a consequence of Fe carbonates dissolution and oxidation involving dissolution/precipitation processes in the sense of Putnis. Non-redox model is a quite plausible origin for subsequent hematite to magnetite conversion.  相似文献   

云南盈江地瓜山钨锡矿矿化特征     

张志平  邹顺坤 《云南地质》2010,29(2):152-155

地瓜山钨锡矿是近年滇西发现的高温热液石英脉型钨锡矿床,矿床产于喜马拉雅期麻蓬岭岗侵入体(Eηγb)与高黎贡山群变质岩接触带内带,近南北向剪切断裂(裂隙)带的有利部位,该区及外围实现找矿重大突破完全有可能。  相似文献   

Mineralogical and chemical distribution patterns of placers and ferricretes in Quaternary sediments in SE Germany: The impact of nature and man on the unroofing of pegmatites     

H.G. Dill  A. Techmer  B. Weber  M. Füßl 《Journal of Geochemical Exploration》2008

Placer deposits mark the ultimate stage of mineral separation in clastic sediments by physical processes in an aquatic regime, whereas duricrusts are an example of extreme element separation by chemical processes in continental environments of deposition. In Quaternary sediments in SE Germany such contrasting types of sediments formed on the NE Bavarian Basement which is underlain by metamorphic and pegmatitic rocks reflecting intense primary element differentiation by themselves.  相似文献   

Stable isotope geochemistry of the Archean Val-d‘Or (Canada) orogenic gold vein field   总被引：2，自引：0，他引：2  

Georges Beaudoin  David Pitre 《Mineralium Deposita》2005,40(1):59-75

A systematic study of the auriferous quartz veins of the Val-dOr vein field, Abitibi, Quebec, Canada, demonstrates that the C, O, S isotope composition of silicate, carbonate, borate, oxide, tungstate and sulphide minerals have a range in composition comparable to that previously determined for the whole Superior Province. The oxygen isotope composition of quartz from early quartz–carbonate auriferous veins ranges from 9.4 to 14.4 whereas later quartz-tourmaline-carbonate veins have ¹⁸O_quartz values ranging from 9.2 to 13.8 . Quartz-carbonate veins have carbonate (¹⁸O: 6.9–12.5 ; ¹³C: –6.2– –1.9 ) and pyrite (³⁴S: 1.2 and 1.9 ) isotope compositions comparable to those of quartz-tourmaline-carbonate veins (¹⁸O: 7.9–11.7 ; ¹³C: –8.0 – –2.4 ; ³⁴S: 0.6–6.0 ). ¹⁸O_quartz values in quartz-tourmaline-carbonate veins have a variance comparable to analytical uncertainty at the scale of one locality, irrespective of the type of structure, the texture of the quartz or its position along strike, across strike or down-dip a vein. In contrast, the oxygen isotope composition of quartz in quartz-tourmaline-carbonate veins displays a regional distribution with higher ¹⁸O values in the south-central part of the vein field near the Cadillac Tectonic Zone, and which ¹⁸O values decrease regularly towards the north. Another zone of high ¹⁸O values in the northeast corner of the region and along the trace of the Senneville Fault is separated by a valley of lower ¹⁸O values from the higher values near the Cadillac Tectonic Zone. Oxygen isotope isopleths cut across lithological contacts and tectonic structures. This regional pattern in quartz-tourmaline-carbonate veins is interpreted to be a product of reaction with country rocks and mixing between (1) a deep-seated hydrothermal fluid of metamorphic origin with minimum ¹⁸O=8.5 , ¹³C=0.6 and ³⁴S=–0.4 , and (2) a supracrustal fluid, most likely Archean seawater with a long history of water-rock exchange and with maximum ¹⁸O=3.9 , ¹³ C=–5.6 and ³⁴S=5.0 .  相似文献